Kőolajipari célú tenzidkompozíciók fejlesztése és vizsgálati módszereinek továbbfejlesztése
Abstract
A kémiai fokozott kőolaj-kitermelésben alkalmazott tenzides és tenzid-polimeres elárasztási technológiák hatékonyságát jelentősen befolyásolja a felhasznált komponensek összetétele, a tárolói közeg tulajdonságai, valamint a formulációban kialakuló kölcsönhatások. Jelen munka célja kőolajipari alkalmazásra szánt tenzidkompozíciók fejlesztéséhez kapcsolódó laboratóriumi vizsgálati módszerek továbbfejlesztése, valamint a tenzid–tenzid, tenzid–koszolvens és tenzid–polimer kölcsönhatások értékelése volt. A kutatás során az emulgeáló hatás vizsgálatát automata demulgeáló berendezés alkalmazásával, az olajkimosó hatás meghatározását üvegkapillárisos módszer kidolgozásával, míg a vízszám-meghatározást oldószercserével fejlesztettem tovább. A vizsgálatok kiterjedtek nagy sótartalmú modell rétegvizekben alkalmazható tenzidkompozíciók oldhatóságára, határfelületi tulajdonságaira, oxo-alkohol típusú koszolvensek hatására, valamint tenzid-polimer rendszerek reológiai viselkedésére. Az eredmények igazolták, hogy a komponensek önálló vizsgálata nem elegendő a gyakorlati alkalmazhatóság megítéléséhez, mivel a teljes formuláció viselkedését a komponensek közötti kölcsönhatások jelentősen módosíthatják. A kidolgozott módszerek és értékelési szempontok hozzájárulhatnak a tárolóspecifikusan optimalizált, ipari szempontból is alkalmazható cEOR-formulációk megbízhatóbb laboratóriumi szelekciójához.
References
1. Pogaku, R.; Mohd Fuat, N. H.; Sakar, S.; Cha, Z. W.; Musa, N.; Awang Tajudin, D. N. A.; Morris, L. O. Polymer flooding and its combinations with other chemical injection methods in enhanced oil recovery. Polymer Bulletin 2018, 75, 1753–1774.
2. Saravanan, S.; Keerthana, S. Floquet instability of gravity-modulated salt fingering in a porous medium. Industrial & Engineering Chemistry Research 2017, 56, 2851–2864.
3. Fakher, S.; Abdelaal, H.; Elgahawy, Y.; Imqam, A. A characterization of different alkali chemical agents for alkaline flooding enhanced oil recovery operations: an experimental investigation. SN Applied Sciences 2019, 1, 1–11.
4. Mandal, A. Chemical Flooding Methods for Enhanced Oil Recovery; CRC Press, 2015.
5. Larson, R. G. The Structure and Rheology of Complex Fluids; Oxford University Press, 1982.
6. Green, D. W.; Willhite, G. P. Enhanced Oil Recovery; Society of Petroleum Engineers: Richardson, TX, 1998.
7. Lake, L. W. Enhanced Oil Recovery; Prentice Hall: Englewood Cliffs, NJ, 1989.
8. Sheng, J. J. Modern Chemical Enhanced Oil Recovery: Theory and Practice; Gulf Professional Publishing: Burlington, MA, 2011.
9. Jing, W.; Huiqing, L.; Genbao, Q.; Yongcan, P.; Yang, G. Investigations on spontaneous imbibition and the influencing factors in tight oil reservoirs. Fuel 2019, 236, 755–768.
10. Khaleel, O.; Teklu, T. W.; Alameri, W.; Abass, H.; Kazemi, H. Wettability alteration of carbonate reservoir cores—laboratory evaluation using complementary techniques. SPE Reservoir Evaluation & Engineering 2019, 22, 911–922.
11. Schön, J. H. Pore space properties. In Developments in Petroleum Science; Elsevier, 2015; Vol. 65, pp 21–84.
12. Wang, J.; Xiao, L.; Liao, G.; Zhang, Y.; Guo, L.; Arns, C. H.; Sun, Z. Theoretical investigation of heterogeneous wettability in porous media using NMR. Scientific Reports 2018, 8, 13450.
13. Yang, J.; Zhou, Y. An automatic in situ contact angle determination based on level set method. Water Resources Research 2020, 56, e2020WR027107.
14. Teletzke, G. F.; Wattenbarger, R. C.; Wilkinson, J. R. Enhanced oil recovery pilot testing best practices. SPE Reservoir Evaluation & Engineering 2010, 13, 143–154.
15. Lu, J.; Liyanage, P. J.; Solairaj, S.; Adkins, S.; Arachchilage, G. P.; Kim, D. H.; Britton, C.; Weerasooriya, U.; Pope, G. A. New surfactant developments for chemical enhanced oil recovery. Journal of Petroleum Science and Engineering 2014, 120, 94–101.
16. Salager, J. L.; Anton, R. E.; Briceño, M. I.; Choplin, L.; Marquez, L.; Pizzino, A.; Rodriguez, M. P. The emergence of formulation engineering in emulsion making—transferring know-how from research laboratory to plant. Polymer International 2003, 52, 471–478.
17. Hartyányi, M.; Nagy, R.; Bartha, L.; Puskás, S. Study on emulsification effect of crude oil in brine emulsions by automated demulsibility tester. Energies 2024, 17, 2438.
18. Massarweh, O.; Abushaikha, A. S. The use of surfactants in enhanced oil recovery: A review of recent advances. Energy Reports 2020, 6, 3150–3178.
19. Cong, Y.; Zhang, W.; Liu, C.; Huang, F. Composition and oil-water interfacial tension studies in different vegetable oils. Food Biophysics 2020, 15, 229–239.
20. Hosseininoosheri, P.; Lashgari, H. R.; Sepehrnoori, K. A novel method to model and characterize in-situ bio-surfactant production in microbial enhanced oil recovery. Fuel 2016, 183, 501–511.
21. Kamal, M. S.; Hussein, I. A.; Sultan, A. S. Review on surfactant flooding: phase behavior, retention, IFT, and field applications. Energy & Fuels 2017, 31, 7701–7720.
22. Ma, K.; Cui, L.; Dong, Y.; Wang, T.; Da, C.; Hirasaki, G. J.; Biswal, S. L. Adsorption of cationic and anionic surfactants on natural and synthetic carbonate materials. Journal of Colloid and Interface Science 2013, 408, 164–172.
23. Bhosle, M. R.; Joshi, S. A.; Bondle, G. M. An efficient contemporary multicomponent synthesis for the facile access to coumarin-fused new thiazolyl chromeno[4,3-b]quinolones in aqueous micellar medium. Journal of Heterocyclic Chemistry 2020, 57, 456–468.
24. Naseri, N.; Ajorlou, E.; Asghari, F.; Pilehvar-Soltanahmadi, Y. An update on nanoparticle-based contrast agents in medical imaging. Artificial Cells, Nanomedicine, and Biotechnology 2018, 46, 1111–1121.
25. Dwarakanath, V.; Chaturvedi, T.; Jackson, A. C.; Malik, T.; Siregar, A.; Zhao, P. Using co-solvents to provide gradients and improve oil recovery during chemical flooding in a light oil reservoir. In SPE Improved Oil Recovery Conference; SPE, 2008; SPE-113965.
26. Puig, J. E.; Scriven, L. E.; Davis, H. T.; Miller, W. G. Roles of co-surfactant and co-solvent in surfactant waterflooding. Chemical Engineering Communications 1988, 65, 169–185.
27. Sahni, V.; Dean, R. M.; Britton, C.; Kim, D. H.; Weerasooriya, U.; Pope, G. A. The role of co-solvents and co-surfactants in making chemical floods robust. In SPE Improved Oil Recovery Conference; SPE, 2010; SPE-130007.
28. Nagy, R.; Hartyányi, M.; Bartha, L.; Puskás, S. Investigation of interaction between viscosity-modifier polymers and surfactants based on vegetable oil for chemical enhanced oil recovery. Chemical Engineering Transactions 2024, 109, 307–312.
29. Hartyányi, M.; Nagy, R.; Bartha, L.; Puskás, S. Tenzidek emulgeáló hatásának meghatározására alkalmazott módszerek összehasonlító vizsgálata. Anyagvizsgálók Lapja 2023, 2023/1, 13–16.
30. Kothencz, R.; Nagy, R.; Bartha, L.; Vágó, Á. Improvement of the selection method of surfactants and their mixtures for chemical enhanced oil recovery. Chemical Engineering Communications 2017, 204, 440–444.
31. Hartyányi, M.; Bejczi, R.; Nagy, R.; Demcsák, N.; Bartha, L.; Puskás, S. An improved method for determining the water number for surfactants. MethodsX 2024, 12, 102671.
32. Bejczi, R.; Hartyányi, M.; Nagy, R.; Demcsák, N.; Bartha, L.; Puskás, S. Development of determination method for the water number of surfactants. In 13th International Colloid Conference; Sitges, Barcelona, Spain, 2024.06.09–12.
33. Hartyányi, M.; Nagy, R.; Bejczi, R.; Bartha, L.; Puskás, S. The impact of salt concentration on the screening of surfactant packages for EOR applications. Energy Science & Engineering 2025.
34. Hartyányi, M.; Nagy, R.; Bartha, L.; Puskás, S. Investigation the solubility of vegetable oil-based nonionic surfactants for the petroleum industry. Chemical Engineering Transactions 2024, 110, 127–132.
35. Hartyányi, M.; Nagy, R.; Bartha, L.; Puskás, S. Kőolajipari célokra előállított tenzidkompozíciók rétegvízben való oldhatóságának vizsgálata. In XXIX. Nemzetközi Vegyészkonferencia; Marosvásárhely, Románia, 2023.10.25–28.
36. Nagy, R.; Hartyányi, M.; Bartha, L.; Puskás, S. Investigation of stability of surfactant solution for CEOR (Chemical Enhanced Oil Recovery). In 13th International Colloid Conference; Sitges, Barcelona, Spain, 2024.06.09–12.
37. Hartyányi, M.; Nagy, R.; Bartha, L.; Puskás, S. Rheological study on surfactant packages and polymers for chemical enhanced oil recovery. In 13th International Colloid Conference; Sitges, Barcelona, Spain, 2024.06.09–12.
38. Nagy, R.; Hartyányi, M.; Bartha, L.; Puskás, S. Study on the interaction between flow-modifier polymers and surfactant mixtures in chemical enhanced oil recovery. In 12th International Colloid Conference; Palma de Mallorca, Spain, 2023.05.11–14.
2. Saravanan, S.; Keerthana, S. Floquet instability of gravity-modulated salt fingering in a porous medium. Industrial & Engineering Chemistry Research 2017, 56, 2851–2864.
3. Fakher, S.; Abdelaal, H.; Elgahawy, Y.; Imqam, A. A characterization of different alkali chemical agents for alkaline flooding enhanced oil recovery operations: an experimental investigation. SN Applied Sciences 2019, 1, 1–11.
4. Mandal, A. Chemical Flooding Methods for Enhanced Oil Recovery; CRC Press, 2015.
5. Larson, R. G. The Structure and Rheology of Complex Fluids; Oxford University Press, 1982.
6. Green, D. W.; Willhite, G. P. Enhanced Oil Recovery; Society of Petroleum Engineers: Richardson, TX, 1998.
7. Lake, L. W. Enhanced Oil Recovery; Prentice Hall: Englewood Cliffs, NJ, 1989.
8. Sheng, J. J. Modern Chemical Enhanced Oil Recovery: Theory and Practice; Gulf Professional Publishing: Burlington, MA, 2011.
9. Jing, W.; Huiqing, L.; Genbao, Q.; Yongcan, P.; Yang, G. Investigations on spontaneous imbibition and the influencing factors in tight oil reservoirs. Fuel 2019, 236, 755–768.
10. Khaleel, O.; Teklu, T. W.; Alameri, W.; Abass, H.; Kazemi, H. Wettability alteration of carbonate reservoir cores—laboratory evaluation using complementary techniques. SPE Reservoir Evaluation & Engineering 2019, 22, 911–922.
11. Schön, J. H. Pore space properties. In Developments in Petroleum Science; Elsevier, 2015; Vol. 65, pp 21–84.
12. Wang, J.; Xiao, L.; Liao, G.; Zhang, Y.; Guo, L.; Arns, C. H.; Sun, Z. Theoretical investigation of heterogeneous wettability in porous media using NMR. Scientific Reports 2018, 8, 13450.
13. Yang, J.; Zhou, Y. An automatic in situ contact angle determination based on level set method. Water Resources Research 2020, 56, e2020WR027107.
14. Teletzke, G. F.; Wattenbarger, R. C.; Wilkinson, J. R. Enhanced oil recovery pilot testing best practices. SPE Reservoir Evaluation & Engineering 2010, 13, 143–154.
15. Lu, J.; Liyanage, P. J.; Solairaj, S.; Adkins, S.; Arachchilage, G. P.; Kim, D. H.; Britton, C.; Weerasooriya, U.; Pope, G. A. New surfactant developments for chemical enhanced oil recovery. Journal of Petroleum Science and Engineering 2014, 120, 94–101.
16. Salager, J. L.; Anton, R. E.; Briceño, M. I.; Choplin, L.; Marquez, L.; Pizzino, A.; Rodriguez, M. P. The emergence of formulation engineering in emulsion making—transferring know-how from research laboratory to plant. Polymer International 2003, 52, 471–478.
17. Hartyányi, M.; Nagy, R.; Bartha, L.; Puskás, S. Study on emulsification effect of crude oil in brine emulsions by automated demulsibility tester. Energies 2024, 17, 2438.
18. Massarweh, O.; Abushaikha, A. S. The use of surfactants in enhanced oil recovery: A review of recent advances. Energy Reports 2020, 6, 3150–3178.
19. Cong, Y.; Zhang, W.; Liu, C.; Huang, F. Composition and oil-water interfacial tension studies in different vegetable oils. Food Biophysics 2020, 15, 229–239.
20. Hosseininoosheri, P.; Lashgari, H. R.; Sepehrnoori, K. A novel method to model and characterize in-situ bio-surfactant production in microbial enhanced oil recovery. Fuel 2016, 183, 501–511.
21. Kamal, M. S.; Hussein, I. A.; Sultan, A. S. Review on surfactant flooding: phase behavior, retention, IFT, and field applications. Energy & Fuels 2017, 31, 7701–7720.
22. Ma, K.; Cui, L.; Dong, Y.; Wang, T.; Da, C.; Hirasaki, G. J.; Biswal, S. L. Adsorption of cationic and anionic surfactants on natural and synthetic carbonate materials. Journal of Colloid and Interface Science 2013, 408, 164–172.
23. Bhosle, M. R.; Joshi, S. A.; Bondle, G. M. An efficient contemporary multicomponent synthesis for the facile access to coumarin-fused new thiazolyl chromeno[4,3-b]quinolones in aqueous micellar medium. Journal of Heterocyclic Chemistry 2020, 57, 456–468.
24. Naseri, N.; Ajorlou, E.; Asghari, F.; Pilehvar-Soltanahmadi, Y. An update on nanoparticle-based contrast agents in medical imaging. Artificial Cells, Nanomedicine, and Biotechnology 2018, 46, 1111–1121.
25. Dwarakanath, V.; Chaturvedi, T.; Jackson, A. C.; Malik, T.; Siregar, A.; Zhao, P. Using co-solvents to provide gradients and improve oil recovery during chemical flooding in a light oil reservoir. In SPE Improved Oil Recovery Conference; SPE, 2008; SPE-113965.
26. Puig, J. E.; Scriven, L. E.; Davis, H. T.; Miller, W. G. Roles of co-surfactant and co-solvent in surfactant waterflooding. Chemical Engineering Communications 1988, 65, 169–185.
27. Sahni, V.; Dean, R. M.; Britton, C.; Kim, D. H.; Weerasooriya, U.; Pope, G. A. The role of co-solvents and co-surfactants in making chemical floods robust. In SPE Improved Oil Recovery Conference; SPE, 2010; SPE-130007.
28. Nagy, R.; Hartyányi, M.; Bartha, L.; Puskás, S. Investigation of interaction between viscosity-modifier polymers and surfactants based on vegetable oil for chemical enhanced oil recovery. Chemical Engineering Transactions 2024, 109, 307–312.
29. Hartyányi, M.; Nagy, R.; Bartha, L.; Puskás, S. Tenzidek emulgeáló hatásának meghatározására alkalmazott módszerek összehasonlító vizsgálata. Anyagvizsgálók Lapja 2023, 2023/1, 13–16.
30. Kothencz, R.; Nagy, R.; Bartha, L.; Vágó, Á. Improvement of the selection method of surfactants and their mixtures for chemical enhanced oil recovery. Chemical Engineering Communications 2017, 204, 440–444.
31. Hartyányi, M.; Bejczi, R.; Nagy, R.; Demcsák, N.; Bartha, L.; Puskás, S. An improved method for determining the water number for surfactants. MethodsX 2024, 12, 102671.
32. Bejczi, R.; Hartyányi, M.; Nagy, R.; Demcsák, N.; Bartha, L.; Puskás, S. Development of determination method for the water number of surfactants. In 13th International Colloid Conference; Sitges, Barcelona, Spain, 2024.06.09–12.
33. Hartyányi, M.; Nagy, R.; Bejczi, R.; Bartha, L.; Puskás, S. The impact of salt concentration on the screening of surfactant packages for EOR applications. Energy Science & Engineering 2025.
34. Hartyányi, M.; Nagy, R.; Bartha, L.; Puskás, S. Investigation the solubility of vegetable oil-based nonionic surfactants for the petroleum industry. Chemical Engineering Transactions 2024, 110, 127–132.
35. Hartyányi, M.; Nagy, R.; Bartha, L.; Puskás, S. Kőolajipari célokra előállított tenzidkompozíciók rétegvízben való oldhatóságának vizsgálata. In XXIX. Nemzetközi Vegyészkonferencia; Marosvásárhely, Románia, 2023.10.25–28.
36. Nagy, R.; Hartyányi, M.; Bartha, L.; Puskás, S. Investigation of stability of surfactant solution for CEOR (Chemical Enhanced Oil Recovery). In 13th International Colloid Conference; Sitges, Barcelona, Spain, 2024.06.09–12.
37. Hartyányi, M.; Nagy, R.; Bartha, L.; Puskás, S. Rheological study on surfactant packages and polymers for chemical enhanced oil recovery. In 13th International Colloid Conference; Sitges, Barcelona, Spain, 2024.06.09–12.
38. Nagy, R.; Hartyányi, M.; Bartha, L.; Puskás, S. Study on the interaction between flow-modifier polymers and surfactant mixtures in chemical enhanced oil recovery. In 12th International Colloid Conference; Palma de Mallorca, Spain, 2023.05.11–14.
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2026-10-09
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